The fibers in carbon composites typically consist of small crystallites of graphite, in which carbon atoms are bonded together in sheets. Within these sheets, atomic bonding is very strong; however, bonding is much weaker between the sheets. This means that graphite is highly anisotropic: it exhibits high stiffness within its plane, but lower stiffness perpendicular to the plane. The manner in which these planes are arranged within a fiber influences the properties of the fiber, which in turn influences the properties of the carbon composite material. A ‘turbostratic’ structure, in which graphite layers are ‘crumpled’ together, tends to exhibit particularly high tensile strength; while an ordered ‘graphitic’ structure offers higher stiffness.
Carbon fibers are generally produced from polymers such as polyacrylonitrile (PAN) or petroleum pitch. These polymers can be formed into thin filaments, which are then wound onto a spool. Heat treatment of these precursor fibers at around 200 to 400°C (392 to 752°F) stabilizes them, and further treatment at around 1000°C (1832°F) removes hydrogen, oxygen, nitrogen, and other non-carbon elements to leave carbon fibers. Different types of precursor fibers and variations in production methods can produce carbon fibers with very different properties. The resulting fibers can be categorized according to their Young modulus, which typically ranges from around 4 GPa to over 500 GPa. Before incorporation into carbon composites, carbon fibers are usually treated to improve their adhesion to the matrix.